Which one of the following has the same number of atoms as are in 6g of H2O?

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  1. 0.4g He
  2. 22g CO2
  3. 1g H2
  4. 12g CO

Answer (Detailed Solution Below)

Option 3 : 1g H2
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CONCEPT:

Number of Atoms in a Given Mass

  • The number of atoms in a given mass of a substance can be calculated using Avogadro's number, which is 6.022 x 1023 atoms per mole.
  • The molar mass of a substance is used to convert the mass of the substance to moles.
  • Once the number of moles is known, it can be multiplied by Avogadro's number to find the number of atoms.

EXPLANATION:

  • First, we calculate the number of moles in 6g of H2O:
    • Molar mass of H2O = 2(1) + 16 = 18 g/mol
    • Number of moles of H2O = mass / molar mass = 6 g / 18 g/mol = 1/3 mol
  • The number of atoms in 1/3 mol of H2O:
    • Each molecule of H2O has 3 atoms (2 hydrogen + 1 oxygen)
    • Total number of atoms = 1/3 mol x 6.022 x 1023 molecules/mol x 3 atoms/molecule = 6.022 x 1023 atoms
      •  0.4g He
        • Molar mass of He = 4 g/mol
        • Number of moles of He = 0.4 g / 4 g/mol = 0.1 mol
        • Number of atoms = 0.1 mol x 6.022 x 1023 atoms/mol = 6.022 x 1022 atoms
      •  22g CO2
        • Molar mass of CO2 = 12 + 2(16) = 44 g/mol
        • Number of moles of CO2 = 22 g / 44 g/mol = 0.5 mol
        • Number of molecules = 0.5 mol x 6.022 x 1023 molecules/mol = 3.011 x 1023 molecules
        • Each molecule of CO2 has 3 atoms (1 carbon + 2 oxygen)
        • Number of atoms = 3.011 x 1023 molecules x 3 atoms/molecule = 9.033 x 1023 atoms
      •  1g H2
        • Molar mass of H2 = 2 g/mol
        • Number of moles of H2 = 1 g / 2 g/mol = 0.5 mol
        • Number of molecules = 0.5 mol x 6.022 x 1023 molecules/mol = 3.011 x 1023 molecules
        • Each molecule of H2 has 2 atoms (2 hydrogen)
        • Number of atoms = 3.011 x 1023 molecules x 2 atoms/molecule = 6.022 x 1023 atoms
      •  12g CO
        • Molar mass of CO = 12 + 16 = 28 g/mol
        • Number of moles of CO = 12 g / 28 g/mol = 0.4286 mol
        • Number of molecules = 0.4286 mol x 6.022 x 1023 molecules/mol = 2.579 x 1023 molecules
        • Each molecule of CO has 2 atoms (1 carbon + 1 oxygen)
        • Number of atoms = 2.579 x 1023 molecules x 2 atoms/molecule = 5.158 x 1023 atoms

Therefore, the correct answer is option 3, which is 1g H2.

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