What is the statement for the second law of thermodynamics?

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Agniveer Vayu Science (Group X) 18 Jan 2023 Memory Based Paper
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  1. Energy of a system is conserved. 
  2. All the spontaneous processes result in decreased total entropy of a system.
  3. All the spontaneous processes result in increased total entropy of a system.
  4. There is no second law of thermodynamics.

Answer (Detailed Solution Below)

Option 3 : All the spontaneous processes result in increased total entropy of a system.
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CONCEPT:

  • The second law of thermodynamics: It states that the total entropy of a system either increases or remains constant in any spontaneous process; it never decreases. 
  • An important implication of this law is that heat transfers energy spontaneously from higher- to lower-temperature objects, but never spontaneously in the reverse direction.
  • This is because entropy increases for heat transfer of energy from hot to cold.

EXPLANATION:

  • Option 1: First law of thermodynamics states that energy is conserved.
  • It says heat given to a system is converted into work done and internal energy.
    • So this is not the correct answer.
  • Option 2 and 3: According to the second law of thermodynamics, The final entropy of a system never decreases.
  • It states that the total entropy of the universe (system + surrounding) must increase in every spontaneous process.
  • So the correct answer is option 3.
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