The solubility product constant expression for Ag3 PO4  3Ag+ + PO is

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OSSTET 2019 (Science PCM) Official Paper (Held on 22 Jan 2020)
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  1. Ksp = [Ag+] [PO]
  2. Ksp = [Ag+] [PO]3
  3. Ksp = [3 Ag+]3 [PO]
  4. Ksp = 3[Ag+] [PO]

Answer (Detailed Solution Below)

Option 3 : Ksp = [3 Ag+]3 [PO]
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Detailed Solution

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Concept:

  • The maximum amount of solute that can be dissolved in a fixed amount of solvent at a given temperature is known as solubility.
  • The solubility equilibrium between the undissolved salt and the dissolved ions exists in a saturated solution.

Explanation:

  • The given sparingly soluble salt is 
  • The solubility expression of this salt is shown below:
  • The equilibrium constant expression in the case of the saturated solution is represented by .
  • It represents the product of the dissolved ions raised to their coefficient powers present in the saturated solution.
  • The expression for the solubility constant  for the given salt is shown below:

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