The major product formed in the following reaction is

F2 Madhuri Teaching 10.01.2023 D18

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CSIR-UGC (NET) Chemical Science: Held on (26 Nov 2020)
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  1. F2 Madhuri Teaching 10.01.2023 D19
  2. F2 Madhuri Teaching 10.01.2023 D20
  3. F2 Madhuri Teaching 10.01.2023 D21
  4. F2 Madhuri Teaching 10.01.2023 D22

Answer (Detailed Solution Below)

Option 2 : F2 Madhuri Teaching 10.01.2023 D20
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Seating Arrangement
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Detailed Solution

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Concept:

Epoxide ring opening followed by carbocation rearrangement:

Explanation:

  • In the presence of HClO4, the compound undergoes epoxide ring openingHClO4 acts as an acid and protonates the O atom of the epoxide.
  • In the next step, the epoxide undergoes ring opening and forms a resonance-stabilized carbocation.
  • The resulting carbocation is a secondary carbocation, which undergoes a rearrangement through [1,2]H shift and finally gives the final product.

F2 Madhuri Teaching 10.01.2023 D23

Conclusion:

Thus, the major product formed in the following reaction is
F2 Madhuri Teaching 10.01.2023 D20 .

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